Matches in SemOpenAlex for { <https://semopenalex.org/work/W2022902911> ?p ?o ?g. }
Showing items 1 to 88 of
88
with 100 items per page.
- W2022902911 abstract "Monomer partitioning between the aqueous and polymer phases in a latex determines many properties of an emulsion polymerization, such as the reaction rate, molecular weight development and, if operated under refluxing conditions, the reaction temperature. A unique two-chamber vapor-liquid equilibrium cell was used during this investigation to obtain an in situ separation of the aqueous phase from the latex, thus permitting a direct determination of the compositions of the aqueous, polymer, and vapor phases in a latex, even under refluxing conditions. Thermodynamic analysis of the vapor-liquid equilibrium problem allows the prediction of the composition of all phases from measured values of the temperature and pressure only. These predictions agreed well with data from other investigations under nonrefluxing conditions and with the aqueous and vapor phase compositions from this investigation. The polymer phase composition data for vinyl acetate polymers with average molecular weights in excess of 106 showed consistently higher polymer volume fractions than predicted. This latter result may be due to crosslinking or strong entanglements resulting from increased chain branching at these high molecular weights." @default.
- W2022902911 created "2016-06-24" @default.
- W2022902911 creator A5062230215 @default.
- W2022902911 creator A5089024475 @default.
- W2022902911 creator A5044029102 @default.
- W2022902911 date "1988-05-01" @default.
- W2022902911 modified "2023-09-26" @default.
- W2022902911 title "Distribution of volatile species in a refluxing polymer colloid" @default.
- W2022902911 doi "https://doi.org/10.1002/aic.690340504" @default.
- W2022902911 hasPublicationYear "1988" @default.
- W2022902911 type Work @default.
- W2022902911 sameAs 2022902911 @default.
- W2022902911 citedByCount "0" @default.
- W2022902911 crossrefType "journal-article" @default.
- W2022902911 hasAuthorship W2022902911A5044029102 @default.
- W2022902911 hasAuthorship W2022902911A5062230215 @default.
- W2022902911 hasAuthorship W2022902911A5089024475 @default.
- W2022902911 hasConcept C121332964 @default.
- W2022902911 hasConcept C127413603 @default.
- W2022902911 hasConcept C149556010 @default.
- W2022902911 hasConcept C158117686 @default.
- W2022902911 hasConcept C15920480 @default.
- W2022902911 hasConcept C166940927 @default.
- W2022902911 hasConcept C178790620 @default.
- W2022902911 hasConcept C184651966 @default.
- W2022902911 hasConcept C185592680 @default.
- W2022902911 hasConcept C188027245 @default.
- W2022902911 hasConcept C19184958 @default.
- W2022902911 hasConcept C192562407 @default.
- W2022902911 hasConcept C199002037 @default.
- W2022902911 hasConcept C20556612 @default.
- W2022902911 hasConcept C206175624 @default.
- W2022902911 hasConcept C2776093513 @default.
- W2022902911 hasConcept C42360764 @default.
- W2022902911 hasConcept C44228677 @default.
- W2022902911 hasConcept C44280652 @default.
- W2022902911 hasConcept C521977710 @default.
- W2022902911 hasConcept C59789625 @default.
- W2022902911 hasConcept C97355855 @default.
- W2022902911 hasConceptScore W2022902911C121332964 @default.
- W2022902911 hasConceptScore W2022902911C127413603 @default.
- W2022902911 hasConceptScore W2022902911C149556010 @default.
- W2022902911 hasConceptScore W2022902911C158117686 @default.
- W2022902911 hasConceptScore W2022902911C15920480 @default.
- W2022902911 hasConceptScore W2022902911C166940927 @default.
- W2022902911 hasConceptScore W2022902911C178790620 @default.
- W2022902911 hasConceptScore W2022902911C184651966 @default.
- W2022902911 hasConceptScore W2022902911C185592680 @default.
- W2022902911 hasConceptScore W2022902911C188027245 @default.
- W2022902911 hasConceptScore W2022902911C19184958 @default.
- W2022902911 hasConceptScore W2022902911C192562407 @default.
- W2022902911 hasConceptScore W2022902911C199002037 @default.
- W2022902911 hasConceptScore W2022902911C20556612 @default.
- W2022902911 hasConceptScore W2022902911C206175624 @default.
- W2022902911 hasConceptScore W2022902911C2776093513 @default.
- W2022902911 hasConceptScore W2022902911C42360764 @default.
- W2022902911 hasConceptScore W2022902911C44228677 @default.
- W2022902911 hasConceptScore W2022902911C44280652 @default.
- W2022902911 hasConceptScore W2022902911C521977710 @default.
- W2022902911 hasConceptScore W2022902911C59789625 @default.
- W2022902911 hasConceptScore W2022902911C97355855 @default.
- W2022902911 hasLocation W20229029111 @default.
- W2022902911 hasOpenAccess W2022902911 @default.
- W2022902911 hasPrimaryLocation W20229029111 @default.
- W2022902911 hasRelatedWork W1968041577 @default.
- W2022902911 hasRelatedWork W1968047014 @default.
- W2022902911 hasRelatedWork W1972566435 @default.
- W2022902911 hasRelatedWork W1992078659 @default.
- W2022902911 hasRelatedWork W1998409078 @default.
- W2022902911 hasRelatedWork W2006891106 @default.
- W2022902911 hasRelatedWork W2010217982 @default.
- W2022902911 hasRelatedWork W2011151077 @default.
- W2022902911 hasRelatedWork W2024944987 @default.
- W2022902911 hasRelatedWork W2030421992 @default.
- W2022902911 hasRelatedWork W2039105800 @default.
- W2022902911 hasRelatedWork W2042540063 @default.
- W2022902911 hasRelatedWork W2045507630 @default.
- W2022902911 hasRelatedWork W2053084135 @default.
- W2022902911 hasRelatedWork W2055036359 @default.
- W2022902911 hasRelatedWork W2060320373 @default.
- W2022902911 hasRelatedWork W2062529416 @default.
- W2022902911 hasRelatedWork W2065825434 @default.
- W2022902911 hasRelatedWork W2067567217 @default.
- W2022902911 hasRelatedWork W2094401148 @default.
- W2022902911 isParatext "false" @default.
- W2022902911 isRetracted "false" @default.
- W2022902911 magId "2022902911" @default.
- W2022902911 workType "article" @default.