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- W2022904275 abstract "Tris-(isopropoxy methylphosphonato) rare earth complexes were obtained by interaction of diisopropyl methylphosphonate with trivalent rare-earth chlorides at 50 °–100 °C. The complexes were characterized by means of infrared, magnetic and X-ray powder diffraction studies. A distorted Oh symmetry is assigned to the metal ions. Far infrared evidence indicates the presence of strong lanthanide (III)-oxygen bonds, possibly having partially covalent character. Possible structures of the new complexes, including monomeric chelates and oligomers or polymers, involving eight-membered phosphonate bridges and four-membered chelate rings, are discussed." @default.
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- W2022904275 date "1970-01-01" @default.
- W2022904275 modified "2023-10-09" @default.
- W2022904275 title "Tris-(isopropoxy methylphosphonato) complexes of trivalent rare-earth metal ions" @default.
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- W2022904275 doi "https://doi.org/10.1016/0022-5088(70)90033-0" @default.
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