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- W2022942368 abstract "Abstract Ammonium plutonium double sulphate tetrahydrate NH4Pu(SO4)2·4H2O and some of its lanthanide isomorphs, i.e. NH4Ln(SO4)2·4H2O (Ln ≡ Y, Dy, Ho and Er) were synthesized and characterized by chemical, thermal and X-ray diffraction methods. The powder data of NH4Pu(SO4)2·4H2O obtained in the present work showed it to be isostructural to NH4Sm(SO4)2·4H2O reported in the literature. All these compounds belonged to the same structural family where the Pu3+ or Ln3+ ion is coordinated to nine oxygen atoms. The unit cells of dysprosium, holmium and erbium compounds showed regular contraction with atomic number. The linear plot of ν 1 3 vs. ionic radii of the lanthanide compounds was used to obtain empirical ionic radii of U3+ and Pu3+ for nine coordination." @default.
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- W2022942368 date "1990-04-01" @default.
- W2022942368 modified "2023-09-25" @default.
- W2022942368 title "Double sulphates of PuIII and some lanthanides with ammonium" @default.
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- W2022942368 doi "https://doi.org/10.1016/0022-5088(90)90126-5" @default.
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