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- W2022961176 abstract "Abstract Starting from elemental powder mixtures of La x Fe 4 Sb 12 ( x = 0.5, 1.0, 1.5), La filled skutterudites were prepared by mechanical alloying (MA) and hot pressing (HP), effect of La addition content on thermoelectric properties was studied in this paper. The as sintered samples were characterized by XRD, EDX and DTA. Owing to the incomplete filling of La, impurities such as Sb and FeSb 2 manifest even at the La content of x = 1.0. Increasing the La addition to x = 1.5, the filled skutterudite phase overwhelms the impurities in the XRD pattern of the hot pressed sample. Over the temperature range of 300–750 K, the Seebeck coefficient and the electrical resistivity of the hot pressed samples increase with the increasing of both La addition and temperature. The thermal conductivity is greatly decreased in comparison with that of unfilled CoSb 3 skutterudite. A maximum ZT of 0.41 was obtained at 750 K with a La content of x = 1.5." @default.
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- W2022961176 date "2006-07-01" @default.
- W2022961176 modified "2023-09-26" @default.
- W2022961176 title "Preparation and thermoelectric properties of La filled skutterudites by mechanical alloying and hot pressing" @default.
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- W2022961176 doi "https://doi.org/10.1016/j.matlet.2005.12.074" @default.
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