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- W2022961574 abstract "Abstract Interaction of polyfluorinated benzocycloalkenes containing four-, five- and six-membered cycles with a number of Lewis acids (SbF 5 , AlCl 3 , AlBr 3 ) have been investigated. An unknown ring expansion of halogenated benzocycloalkenes has been found when perfluoro-1-methylbenzocyclobutene (I) was reacted with Lewis acids. Perfluoroindane was formed under heating of compound (I) with SbF 5 . The interaction of compound (1) with AlBr 3 (25–30°C) depends on the amounts of AlBr 3 and gives compounds (II) or (IV), or a mixture of compounds (II), (III) and (IV). Some of the investigated transformations are shown on the scheme. The ring expansion in these reactions perhaps proceeds via intermediate cation (V) (or crypto-ion). Some reactions of compound (IV) and other compounds have been investigated. The reaction pathways of the titled transformations will be discussed." @default.
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- W2022961574 date "1980-12-01" @default.
- W2022961574 modified "2023-09-26" @default.
- W2022961574 title "Interaction of polyfluorinated benzo-cycloalkenes with lewis acids. Skeleton rearrangements in these reactions" @default.
- W2022961574 doi "https://doi.org/10.1016/s0022-1139(00)84068-3" @default.
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