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- W2022962497 abstract "Dehydrofluorination of alkoxydifluorophosphoranes 2, containing chiral alkoxygroup, by organometallic bases passes under conditions of kinetic control to afford diastereomeres of ylid 3 in the proportion 1:1. In the presence of lithium salts the epimerization of 3 leads to the formation of the most thermodynamic stable diastereomere. Hydrolysis and reaction of 3 with alcohols affords phosphinates 6, reaction with acids provides fluorophosphinates 7." @default.
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- W2022962497 date "1994-03-01" @default.
- W2022962497 modified "2023-09-27" @default.
- W2022962497 title "Fluoroalkoxyphosphonium ylids. Epimerization and transformations" @default.
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