Matches in SemOpenAlex for { <https://semopenalex.org/work/W2022962662> ?p ?o ?g. }
- W2022962662 endingPage "833" @default.
- W2022962662 startingPage "827" @default.
- W2022962662 abstract "The intrinsic properties of orthorhombic Hamiltonians, e.g. zero-field splitting (ZFS) ones or crystal-field (CF) ones, embodied in the standardization idea may be utilized to improve reliability and comparability of experimentally determined ZFS (or CF) parameters. These properties have enabled derivation of transformation relations for Hamiltonian parameters expressed in several related axis systems defined earlier by one of us. In this paper the standardization transformations are used to generate alternative physically equivalent yet numerically distinct parameter sets for Mn2+ ions in various hosts exhibiting orthorhombic or lower site symmetry. One parameter set out of six alternative sets satisfies the standardization criteria. Importantly, the standardized sets should be used for direct comparisons. Several non-standard ZFS parameter (ZFSP) sets for Mn2+ ions in crystals, identified in our literature survey of EMR studies, are here standardized. Thus the ratio of λ=E/D or λ′=B22/B20 is limited to the standard range (0, ±1/3) or (0, ±1), respectively. Our considerations provide useful correlations between the distinct and non-compatible yet physically equivalent ZFS parameter sets reported in literature. All calculated alternative sets are tabularized for ten Mn2+ complexes considered. These ZFSP sets may serve for application of the multiple correlated fitting techniques in follow-up EMR studies. Some misinterpretations yielding ambiguous and unreliable results are clarified. The intricate low symmetry aspects are also discussed, whenever applicable. The results of this paper enable more reliable analysis, comparison, and fitting of ZFSP sets from EMR spectra for Mn2+ ions in various crystals." @default.
- W2022962662 created "2016-06-24" @default.
- W2022962662 creator A5032558717 @default.
- W2022962662 creator A5038696318 @default.
- W2022962662 creator A5063517989 @default.
- W2022962662 creator A5076452276 @default.
- W2022962662 date "2009-05-01" @default.
- W2022962662 modified "2023-10-10" @default.
- W2022962662 title "Alternative zero-field splitting (ZFS) parameter sets and standardization for Mn2+ ions in various hosts exhibiting orthorhombic site symmetry" @default.
- W2022962662 cites W1601898396 @default.
- W2022962662 cites W1613154505 @default.
- W2022962662 cites W1618656240 @default.
- W2022962662 cites W1638076916 @default.
- W2022962662 cites W1965182819 @default.
- W2022962662 cites W1965927183 @default.
- W2022962662 cites W1966031549 @default.
- W2022962662 cites W1967580645 @default.
- W2022962662 cites W1968769605 @default.
- W2022962662 cites W1970146484 @default.
- W2022962662 cites W1971610462 @default.
- W2022962662 cites W1972632108 @default.
- W2022962662 cites W1974496101 @default.
- W2022962662 cites W1974658096 @default.
- W2022962662 cites W1977553476 @default.
- W2022962662 cites W1978008514 @default.
- W2022962662 cites W1979712899 @default.
- W2022962662 cites W1982754041 @default.
- W2022962662 cites W1985738180 @default.
- W2022962662 cites W1989203801 @default.
- W2022962662 cites W1989540100 @default.
- W2022962662 cites W1993281367 @default.
- W2022962662 cites W1996101925 @default.
- W2022962662 cites W2000797713 @default.
- W2022962662 cites W2004230281 @default.
- W2022962662 cites W2009191160 @default.
- W2022962662 cites W2016486044 @default.
- W2022962662 cites W2017841908 @default.
- W2022962662 cites W2020210523 @default.
- W2022962662 cites W2022134399 @default.
- W2022962662 cites W2024783560 @default.
- W2022962662 cites W2028123327 @default.
- W2022962662 cites W2031391746 @default.
- W2022962662 cites W2034111652 @default.
- W2022962662 cites W2034646106 @default.
- W2022962662 cites W2036209696 @default.
- W2022962662 cites W2037843114 @default.
- W2022962662 cites W2039877565 @default.
- W2022962662 cites W2045348704 @default.
- W2022962662 cites W2049318371 @default.
- W2022962662 cites W2051691870 @default.
- W2022962662 cites W2061613781 @default.
- W2022962662 cites W2068248697 @default.
- W2022962662 cites W2068646842 @default.
- W2022962662 cites W2071590124 @default.
- W2022962662 cites W2071897227 @default.
- W2022962662 cites W2072117478 @default.
- W2022962662 cites W2074656764 @default.
- W2022962662 cites W2077313588 @default.
- W2022962662 cites W2085399313 @default.
- W2022962662 cites W2091420593 @default.
- W2022962662 cites W2092289501 @default.
- W2022962662 cites W2092919544 @default.
- W2022962662 cites W2124011825 @default.
- W2022962662 cites W2124973429 @default.
- W2022962662 cites W2140998015 @default.
- W2022962662 cites W2169143798 @default.
- W2022962662 cites W29100603 @default.
- W2022962662 cites W3031341840 @default.
- W2022962662 cites W4246785171 @default.
- W2022962662 cites W46035612 @default.
- W2022962662 doi "https://doi.org/10.1016/j.jpcs.2009.04.003" @default.
- W2022962662 hasPublicationYear "2009" @default.
- W2022962662 type Work @default.
- W2022962662 sameAs 2022962662 @default.
- W2022962662 citedByCount "42" @default.
- W2022962662 countsByYear W20229626622012 @default.
- W2022962662 countsByYear W20229626622013 @default.
- W2022962662 countsByYear W20229626622014 @default.
- W2022962662 countsByYear W20229626622015 @default.
- W2022962662 countsByYear W20229626622016 @default.
- W2022962662 countsByYear W20229626622017 @default.
- W2022962662 countsByYear W20229626622018 @default.
- W2022962662 countsByYear W20229626622019 @default.
- W2022962662 countsByYear W20229626622020 @default.
- W2022962662 countsByYear W20229626622021 @default.
- W2022962662 crossrefType "journal-article" @default.
- W2022962662 hasAuthorship W2022962662A5032558717 @default.
- W2022962662 hasAuthorship W2022962662A5038696318 @default.
- W2022962662 hasAuthorship W2022962662A5063517989 @default.
- W2022962662 hasAuthorship W2022962662A5076452276 @default.
- W2022962662 hasBestOaLocation W20229626622 @default.
- W2022962662 hasConcept C111919701 @default.
- W2022962662 hasConcept C114614502 @default.
- W2022962662 hasConcept C115624301 @default.
- W2022962662 hasConcept C121332964 @default.
- W2022962662 hasConcept C126255220 @default.
- W2022962662 hasConcept C130787639 @default.
- W2022962662 hasConcept C145148216 @default.