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- W2022962786 abstract "The kinetic salt effect in the 18O-exchange reaction between bromate ion and water has been investigated at 60° in a range of ionic strength from 0.02M < I < 1.9M using NaNO3 or NaClO4 as inert salts. From the experimental data the following relation was deduced for the uncatalysed reaction path In the H+-catalysed reaction path the Brønsted-Davies equation was obeyed up to I ⋍ 0.1M At I > 0.8M the sign of Δ logk2/Δ I1/2 was positive. The theoretical interpretation of these results is consistent with the mechanistic evidence obtained previously from the rate law and the solvent isotope effects." @default.
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- W2022962786 date "1972-07-10" @default.
- W2022962786 modified "2023-09-23" @default.
- W2022962786 title "Kinetic Salt Effect in the<sup>18</sup>O-Exchange Reaction between Bromate and Water" @default.
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