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- W2022962804 abstract "Die Umsetzung von Tricarbonyl(η6-phenyllithium)chrom mit den Metallhexacarbonylen der VI. Nebengruppe und anschließende Alkylierung mittels Triethyloxonium-tetrafluoroborat führt zu Pentacarbonyl{ethoxy[(tricarbonylchrom)-η6-phenyl]carben}-Verbindungen des Chroms, Molybdäns und Wolframs (1 – 3). 1 und 3 reagieren mit den Bortrihalogeniden BX3 (X = Cl, Br) unter Abspaltung der Ethoxygruppe zu den trans-Tetracarbonylhalogeno[(tricarbonylchrom)-η6-phenylcarbin]metall-Komplexen 4 – 7. Eigenschaften und spektroskopische Ergebnisse sowie die Röntgenstrukturanalyse von 6 werden diskutiert. Transition Metal Carbyne Complexes, LII. (Tricarbonylchromium)-η6-phenyl as Substituent in Carbene- and Carbyne Complexes of the VI. Subgroup The reaction of tricarbonyl(η6-phenyllithium)chromium with the metalhexacarbonyls of the VI. subgroup and subsequent alkylation by triethyloxonium tetrafluoroborate yields pentacarbonyl-{ethoxy[(tricarbonylchromium)-η6-phenyl]carbene} complexes of chromium, molybdenum, and tungsten (1 – 3). 1 and 3 react with boron trihalides BX3 (X = Cl, Br) by cleavage of the ethoxy group to form trans-tetracarbonylhalogeno[(tricarbonylchromium)-η6-phenylcarbyne]metal complexes 4 – 7. Properties, spectroscopic results, and the X-ray structure analysis of 6 are discussed." @default.
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- W2022962804 title "Übergangsmetall‐Carbin‐Komplexe, LII. (Tricarbonylchrom)‐η; <sup>6</sup> ‐phenyl als Substituent in Carben‐ und Carbinkomplexen der VI. Nebengruppe" @default.
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- W2022962804 doi "https://doi.org/10.1002/cber.19801130320" @default.
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