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- W2022971453 abstract "Series of neoglycolipids containing cholesteryl and N-acetyl-d-glucosaminyl groups were synthesized with various ethoxy linkers. Their self aggregations and intermolecular interactions, without and with egg yolk phosphatidylcholine (EYPC), were characterized in dry and hydrated states, by using infrared spectroscopy. The neoglycolipids in the dry state formed intermolecular hydrogen bonds between the CO and N–H or O–H groups of N-acetyl-d-glucosamine (GlcNAc). In the presence of EYPC, these intermolecular interactions were broken and new hydrogen bonds, involving the phosphate group of EYPC and N–H or O–H groups of GlcNAc of neoglycolipid, were formed. The presence of water molecules altered these intermolecular hydrogen bonds. The CO groups of EYPC were not affected by the presence of neoglycolipids, either in hydrated or in dry states, indicating that the GlcNAc polar groups interacted mostly with EYPC phosphate residues. The phase transition-temperature of mixtures of EYPC containing either cholesterol or neoglycolipid were similar, indicating that the cholesteryl group of the neoglycolipid interacted in the same manner as cholesterol with hydrocarbon chains of EYPC. Some structural models of molecular interactions of neoglycolipids were discussed in relation with the molecular recognition of wheat germ agglutinin." @default.
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- W2022971453 date "1999-03-01" @default.
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- W2022971453 title "Interactions of egg yolk phosphatidylcholine with cholesteryl polyethoxy neoglycolipids containing N-acetyl-d-glucosamine" @default.
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- W2022971453 doi "https://doi.org/10.1016/s0022-2860(98)00800-x" @default.
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