Matches in SemOpenAlex for { <https://semopenalex.org/work/W2022975209> ?p ?o ?g. }
- W2022975209 endingPage "159" @default.
- W2022975209 startingPage "155" @default.
- W2022975209 abstract "Trinuclear selenolate complexes [(CO)4Mn(μ-SeR)2Ni(μ-SeR)2Mn(CO)4] (R=Me, Ph) containing a distorted square planar Ni(Se)4 core have been synthesized by the reaction of Ni(NO3)2 · 6H2O/NiCl2 with the chelating metalloligand cis-[PPN][Mn(CO)4(SeR)2] in MeCN. Their structures were elucidated on the basis of IR, UV–Vis, CV, and NMR spectra. X-ray crystallography confirmed the heterotrinuclear structure in the solid state with a NiII–Se distance of 2.331(1) Å, and a NiII⋯MnI distance of 3.428(2) Å (average). The dependence of geometry on electron population and the larger NiII⋯MnI distances are adopted to rationalize the construction of the complex [(CO)4Mn(μ-SeMe)2Ni(μ-SeMe)2Mn(CO)4] with a distorted square planar NiII(Se)4 core. Further reaction of cis-[PPN][Mn(CO)4(SePh)2] with PdCl2 afforded [PPN]2[Cl2Pd(μ-SePh)2PdCl2]. Its structure has been determined. This investigation shows that cis-[Mn(CO)4(SeR)2]− serves as a chelating metalloligand and selenolate ligand-transfer reagent." @default.
- W2022975209 created "2016-06-24" @default.
- W2022975209 creator A5009014980 @default.
- W2022975209 creator A5032236059 @default.
- W2022975209 creator A5045766004 @default.
- W2022975209 creator A5057574653 @default.
- W2022975209 creator A5073056697 @default.
- W2022975209 date "1999-03-01" @default.
- W2022975209 modified "2023-09-26" @default.
- W2022975209 title "Chelating and ligand-transfer studies of the complexes cis-[Mn(CO)4(SeR)2]−: crystal structures of heterotrinuclear [(CO)4Mn(μ-SeMe)2Ni(μ-SeMe)2Mn(CO)4] with a distorted square planar NiII–selenolate core and [PPN]2[Cl2Pd(μ-SePh)2PdCl2]" @default.
- W2022975209 cites W1964089401 @default.
- W2022975209 cites W1968079407 @default.
- W2022975209 cites W1970361825 @default.
- W2022975209 cites W1978621590 @default.
- W2022975209 cites W1978750868 @default.
- W2022975209 cites W1980899397 @default.
- W2022975209 cites W1981125958 @default.
- W2022975209 cites W1996305812 @default.
- W2022975209 cites W1996547536 @default.
- W2022975209 cites W2003268082 @default.
- W2022975209 cites W2009150936 @default.
- W2022975209 cites W2013691774 @default.
- W2022975209 cites W2022955259 @default.
- W2022975209 cites W2025983387 @default.
- W2022975209 cites W2028232902 @default.
- W2022975209 cites W2030077385 @default.
- W2022975209 cites W2030535049 @default.
- W2022975209 cites W2034935602 @default.
- W2022975209 cites W2035792893 @default.
- W2022975209 cites W2044737217 @default.
- W2022975209 cites W2049713811 @default.
- W2022975209 cites W2050989731 @default.
- W2022975209 cites W2052432341 @default.
- W2022975209 cites W2057737673 @default.
- W2022975209 cites W2059401704 @default.
- W2022975209 cites W2060244499 @default.
- W2022975209 cites W2067553457 @default.
- W2022975209 cites W2069479627 @default.
- W2022975209 cites W2069715500 @default.
- W2022975209 cites W2072866010 @default.
- W2022975209 cites W2075985191 @default.
- W2022975209 cites W2082582131 @default.
- W2022975209 cites W2083896487 @default.
- W2022975209 cites W2086547565 @default.
- W2022975209 cites W2091303527 @default.
- W2022975209 cites W2092750882 @default.
- W2022975209 cites W2094011081 @default.
- W2022975209 cites W2096856569 @default.
- W2022975209 cites W2151700042 @default.
- W2022975209 cites W2325201273 @default.
- W2022975209 cites W2952201267 @default.
- W2022975209 doi "https://doi.org/10.1016/s0020-1693(98)00395-8" @default.
- W2022975209 hasPublicationYear "1999" @default.
- W2022975209 type Work @default.
- W2022975209 sameAs 2022975209 @default.
- W2022975209 citedByCount "9" @default.
- W2022975209 countsByYear W20229752092019 @default.
- W2022975209 crossrefType "journal-article" @default.
- W2022975209 hasAuthorship W2022975209A5009014980 @default.
- W2022975209 hasAuthorship W2022975209A5032236059 @default.
- W2022975209 hasAuthorship W2022975209A5045766004 @default.
- W2022975209 hasAuthorship W2022975209A5057574653 @default.
- W2022975209 hasAuthorship W2022975209A5073056697 @default.
- W2022975209 hasBestOaLocation W20229752092 @default.
- W2022975209 hasConcept C112887158 @default.
- W2022975209 hasConcept C115624301 @default.
- W2022975209 hasConcept C116569031 @default.
- W2022975209 hasConcept C121684516 @default.
- W2022975209 hasConcept C134786449 @default.
- W2022975209 hasConcept C144024400 @default.
- W2022975209 hasConcept C147789679 @default.
- W2022975209 hasConcept C149923435 @default.
- W2022975209 hasConcept C170493617 @default.
- W2022975209 hasConcept C178790620 @default.
- W2022975209 hasConcept C179104552 @default.
- W2022975209 hasConcept C185592680 @default.
- W2022975209 hasConcept C194196696 @default.
- W2022975209 hasConcept C197404232 @default.
- W2022975209 hasConcept C2908647359 @default.
- W2022975209 hasConcept C32909587 @default.
- W2022975209 hasConcept C40875361 @default.
- W2022975209 hasConcept C41008148 @default.
- W2022975209 hasConcept C55493867 @default.
- W2022975209 hasConcept C71240020 @default.
- W2022975209 hasConcept C8010536 @default.
- W2022975209 hasConceptScore W2022975209C112887158 @default.
- W2022975209 hasConceptScore W2022975209C115624301 @default.
- W2022975209 hasConceptScore W2022975209C116569031 @default.
- W2022975209 hasConceptScore W2022975209C121684516 @default.
- W2022975209 hasConceptScore W2022975209C134786449 @default.
- W2022975209 hasConceptScore W2022975209C144024400 @default.
- W2022975209 hasConceptScore W2022975209C147789679 @default.
- W2022975209 hasConceptScore W2022975209C149923435 @default.
- W2022975209 hasConceptScore W2022975209C170493617 @default.
- W2022975209 hasConceptScore W2022975209C178790620 @default.
- W2022975209 hasConceptScore W2022975209C179104552 @default.
- W2022975209 hasConceptScore W2022975209C185592680 @default.
- W2022975209 hasConceptScore W2022975209C194196696 @default.