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• W2022981075 abstract "Abstract—The title complex (2) has been synthesized by 1:1 reaction of [NBu][Pt(C F)(μ-C F)] with [Ag(OClO)(SC H)] in CH C1. The structure of 2·0.5C Hhas been determined by single-crystal X-ray diffraction methods. Complex 2 contains two Pt—Ag bonds unsupported by other covalent bridges [Pt(l)—Ag = 2.799(1), Pt(2)—Ag = 2.824(1) ]. The platinum atoms are bridged by two pentafiuorophenyl groups and the silver atom. The bridging pentafiuorophenyl groups are oriented in such a way that the silver atom makes short contacts with two of their ortho-fluorine atoms [AgF(30) = 2.643(5), AgF(32) = 2.716(6) ]. These o-FAg contacts can also be observed in the 19F NMR spectrum of 2. This is the first time that such contacts have been detected in solution. Copyright © 1996 Elsevier Science Ltd" @default.
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• W2022981075 date "1996-07-01" @default.
• W2022981075 modified "2023-10-17" @default.
• W2022981075 title "Synthesis and x-ray structure of [NBu][Pt(CF)(μ-C F) μ-Ag(SC H )] (SC H = tetrahydrothiophene). evidence of the existence of intramolecular AgF interactions in solution and in the solid state" @default.
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• W2022981075 doi "https://doi.org/10.1016/0277-5387(96)00070-8" @default.
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