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- W2022981972 abstract "Treatment of 4-chloro-6-dialkylaminopyrimidine-5-carbaldehydes (4) with boiling water or dilute acetic or hydrochloric acid gave corresponding 3-dialkylamino-3-iminopropiononitriles (11) by ring cleavage and deformylation. The acid-catalysed deformylations, which followed ring cleavage, proceeded under extremely mild conditions and the formyl groups were lost as formic acid. Mechanisms for the ring cleavages and deformylations are proposed." @default.
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- W2022981972 date "1976-01-01" @default.
- W2022981972 modified "2023-09-23" @default.
- W2022981972 title "Heterocyclic studies. Part XXXVII. Ready ring cleavage and decarbonylation of pyrimidine-5-carbaldehydes" @default.
- W2022981972 doi "https://doi.org/10.1039/p19760000125" @default.
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