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• W2022984346 abstract "The wave functions of columnar metal cluster compounds can be expressed as an expansion based on the particle on the cylinder problem. Main group columnar clusters are characterised by n + 1 skeletal and 2n − 1 ‘unavailable’ molecular orbitals. Transition metal columnar clusters also have 2n − 1 ‘unavailable’ molecular orbitals with a high proportion of p orbital character and additional ‘unavailable’ orbitals from the dδ set of atomic orbitals. The number of these orbitals and their symmetries have been derived from a particle on a cylinder analysis. This bonding analysis has been applied to clusters containing columns of triangles and squares." @default.
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• W2022984346 date "1988-02-01" @default.
• W2022984346 modified "2023-09-23" @default.
• W2022984346 title "Theoretical analysis of cluster compounds with cylindrical topologies" @default.
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• W2022984346 doi "https://doi.org/10.1016/s0022-328x(00)99398-7" @default.
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