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• W2022985912 abstract "The decomposition of 4-methylpyrimidine was studied behind reflected shock waves in a pressurized driver single-pulse shock tube over the temperature range 1160−1330 K at overall densities of ∼3 × 10-5 mol/cm3. A plethora of decomposition products, both with and without nitrogen was found in the post-shock mixtures. They were HCN, CH3CN, C2H3CN, pyrimidine, C2H5CN, cis- and trans-CH3CHCHCN, CH2CHCH2CN, CH⋮C−CN, and C2N2, among the nitrogen containing products, and CH4, C2H2, CH3C⋮CH, C2H6, CH2CCH2, and C2H4 as products without nitrogen. It is suggested that the decomposition of 4-methylpyrimidine has two major initiation steps. (1) An ejection of a hydrogen atom from the methyl group that is connected to the ring, C4H3N2−CH3 → C4H3N2−CH2• + H•, and (2) split of the methyl group from the ring, C4H3N2−CH3 → C4H3N2• + CH3•. The ejection of H atom from the ring is much slower and does not contribute much to the total rate. The H atoms and methyl radicals initiate a chain mechanism by abstraction of an H atom ..." @default.
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• W2022985912 date "2001-03-21" @default.
• W2022985912 modified "2023-09-27" @default.
• W2022985912 title "Thermal Decomposition of 4-Methylpyrimidine. Experimental Results and Kinetic Modeling" @default.
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• W2022985912 doi "https://doi.org/10.1021/jp0040392" @default.
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