FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W2022986026> ?p ?o ?g. }

• W2022986026 endingPage "7017" @default.
• W2022986026 startingPage "7011" @default.
• W2022986026 abstract "We report the site-specific synthesis of mixed valence TiIV−O−FeII complexes within the pores of ordered mesoporous silica (SBA-15). By using 6-di-tert-butylpyridine as the selective activator of tripodally linked TiIV−OH groups of Ti-grafted SBA-15, the FeCl2·4H2O complexes reacted selectively with the nucleophilic TiIV−O− groups. The formation of Si−O−FeII byproducts, due to the reaction with the abundant Si−OH groups, was successfully restricted and the selectivity for forming the TiIV−O−FeII complexes exceeded 80%. The metal−metal interaction of TiIV−O−FeII complexes was confirmed by the appearance of TiIV/FeII → TiIII/FeIII metal-to-metal charge transfer band, and their coordination, valency, and spin state were characterized by diffuse transmission UV−vis, Fourier transform IR, and Fe K-edge X-ray absorption fine structure measurements. It was also confirmed that the present methods can be extended to other metal combinations of TiIV−O−NiII and TiIV−O−MnII. The electron transfer processes occurring under photoinduced metal-to-metal charge transfer of oxo-bridged mixed valence complexes on silica supports have recently been proven as a new class of visible-light-sensitive redox centers. Thus, the present synthetic procedure allows the fabrication of a variety of photochemical reaction centers according to the molecular-level design." @default.
• W2022986026 created "2016-06-24" @default.
• W2022986026 creator A5039144618 @default.
• W2022986026 creator A5040346832 @default.
• W2022986026 creator A5042397338 @default.
• W2022986026 creator A5047385896 @default.
• W2022986026 date "2008-05-27" @default.
• W2022986026 modified "2023-10-18" @default.
• W2022986026 title "Site-Specific Synthesis of Oxo-Bridged Mixed-Valence Binuclear Complexes on Mesoporous Silica" @default.
• W2022986026 cites W1531823955 @default.
• W2022986026 cites W1967205515 @default.
• W2022986026 cites W1972417875 @default.
• W2022986026 cites W1974911403 @default.
• W2022986026 cites W1982183246 @default.
• W2022986026 cites W1983625412 @default.
• W2022986026 cites W1985791832 @default.
• W2022986026 cites W1988245545 @default.
• W2022986026 cites W1988745485 @default.
• W2022986026 cites W1990342615 @default.
• W2022986026 cites W1996505261 @default.
• W2022986026 cites W1998606495 @default.
• W2022986026 cites W1998735072 @default.
• W2022986026 cites W2003819407 @default.
• W2022986026 cites W2005224133 @default.
• W2022986026 cites W2005569848 @default.
• W2022986026 cites W2008523417 @default.
• W2022986026 cites W2014515645 @default.
• W2022986026 cites W2016592851 @default.
• W2022986026 cites W2018189315 @default.
• W2022986026 cites W2018255641 @default.
• W2022986026 cites W2020402202 @default.
• W2022986026 cites W2020702410 @default.
• W2022986026 cites W2021521768 @default.
• W2022986026 cites W2021720370 @default.
• W2022986026 cites W2022256605 @default.
• W2022986026 cites W2025838508 @default.
• W2022986026 cites W2028479590 @default.
• W2022986026 cites W2035477648 @default.
• W2022986026 cites W2038118870 @default.
• W2022986026 cites W2041244746 @default.
• W2022986026 cites W2043001072 @default.
• W2022986026 cites W2046471185 @default.
• W2022986026 cites W2048988726 @default.
• W2022986026 cites W2057820608 @default.
• W2022986026 cites W2059954377 @default.
• W2022986026 cites W2063296173 @default.
• W2022986026 cites W2065316535 @default.
• W2022986026 cites W2068395379 @default.
• W2022986026 cites W2078171437 @default.
• W2022986026 cites W2083849442 @default.
• W2022986026 cites W2089605181 @default.
• W2022986026 cites W2090438318 @default.
• W2022986026 cites W2090670768 @default.
• W2022986026 cites W2092012364 @default.
• W2022986026 cites W2100677720 @default.
• W2022986026 cites W2105510993 @default.
• W2022986026 cites W2111062994 @default.
• W2022986026 cites W27191216 @default.
• W2022986026 cites W2949524823 @default.
• W2022986026 doi "https://doi.org/10.1021/la704032c" @default.
• W2022986026 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/18503283" @default.
• W2022986026 hasPublicationYear "2008" @default.
• W2022986026 type Work @default.
• W2022986026 sameAs 2022986026 @default.
• W2022986026 citedByCount "29" @default.
• W2022986026 countsByYear W20229860262012 @default.
• W2022986026 countsByYear W20229860262013 @default.
• W2022986026 countsByYear W20229860262014 @default.
• W2022986026 countsByYear W20229860262016 @default.
• W2022986026 countsByYear W20229860262017 @default.
• W2022986026 countsByYear W20229860262018 @default.
• W2022986026 countsByYear W20229860262020 @default.
• W2022986026 countsByYear W20229860262021 @default.
• W2022986026 countsByYear W20229860262022 @default.
• W2022986026 crossrefType "journal-article" @default.
• W2022986026 hasAuthorship W2022986026A5039144618 @default.
• W2022986026 hasAuthorship W2022986026A5040346832 @default.
• W2022986026 hasAuthorship W2022986026A5042397338 @default.
• W2022986026 hasAuthorship W2022986026A5047385896 @default.
• W2022986026 hasConcept C110715899 @default.
• W2022986026 hasConcept C121332964 @default.
• W2022986026 hasConcept C123669783 @default.
• W2022986026 hasConcept C138885662 @default.
• W2022986026 hasConcept C139007053 @default.
• W2022986026 hasConcept C161790260 @default.
• W2022986026 hasConcept C168900304 @default.
• W2022986026 hasConcept C178790620 @default.
• W2022986026 hasConcept C178907741 @default.
• W2022986026 hasConcept C179104552 @default.
• W2022986026 hasConcept C185592680 @default.
• W2022986026 hasConcept C2777496208 @default.
• W2022986026 hasConcept C2778591166 @default.
• W2022986026 hasConcept C32891209 @default.
• W2022986026 hasConcept C41895202 @default.
• W2022986026 hasConcept C544153396 @default.
• W2022986026 hasConcept C55904794 @default.
• W2022986026 hasConcept C62520636 @default.
• W2022986026 hasConcept C75473681 @default.

• next