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- W2022987835 abstract "The reactions of [ReOX 3 (AsPh 3 ) 2 ] (X = Cl, Br) with 4,7-diphenyl-1,10-phenanthroline (dpphen) have been examined and the complexes [ReO(OMe)X 2 (dpphen)] and [Re 2 O 3 X 4 (dpphen) 2 ]·2/3CH 2 Cl 2 (X = Cl, Br) have been obtained. They were characterised by IR, UV–Vis spectroscopy, and single crystal X-ray analysis has been performed for [ReO(OMe)Cl 2 (dpphen)] and [Re 2 O 3 Br 4 (dpphen) 2 ]·2/3CH 2 Cl 2 . The nature of the frontier orbitals of [ReO(OMe)Cl 2 (dpphen)] and [Re 2 O 3 Br 4 (dpphen) 2 ] and the electronic transitions involved in the absorption spectra have been studied by means of the density functional and time-dependent density functional methods. The reactions of [ReOX 3 (AsPh 3 ) 2 ] (X = Cl, Br) with 4,7-diphenyl-1,10-phenanthroline (dpphen) have been examined and the complexes [ReO(OMe)X 2 (dpphen)] and [Re 2 O 3 X 4 (dpphen) 2 ]·2/3CH 2 Cl 2 (X = Cl, Br) have been obtained. They were characterized by IR, UV–Vis spectroscopy, and single crystal X-ray analysis has been performed for [ReO(OMe)Cl 2 (dpphen)] and [Re 2 O 3 Br 4 (dpphen) 2 ]·2/3CH 2 Cl 2 . The nature of the frontier orbitals of [ReO(OMe)Cl 2 (dpphen)] and [Re 2 O 3 Br 4 (dpphen) 2 ] and the electronic transitions involved in the absorption spectra have been studied by means of the density functional and time-dependent density functional methods." @default.
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- W2022987835 date "2009-12-01" @default.
- W2022987835 modified "2023-09-27" @default.
- W2022987835 title "Mono- and di-nuclear oxorhenium(V) complexes of 4,7-diphenyl-1,10-phenanthroline" @default.
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- W2022987835 doi "https://doi.org/10.1016/j.poly.2009.08.036" @default.
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