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- W2022989756 abstract "Abstract Carbazoles, unsubstituted in the 9-position, have been prepared by applying the Pschorr reaction to N-acetyl-2-aminodiphenylamines. When applied to the preparation of carbazole itself and 2-trifluoromethylcarbazole the reaction was straightforward. When applied to the formation of 4-trifluoromethylcarbazole, the reaction gave the carbazole or the corresponding triazole or benziminazole depending upon the conditions used. It has been shown that the benziminazole can be formed by incorporating one of the nitrogen atoms of the diazonium intermediate into the heterocyclic ring. A mechanism is proposed for this novel reaction. 3-Trifluoromethyldiphenylamine has been prepared by standard methods." @default.
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- W2022989756 date "1960-01-01" @default.
- W2022989756 modified "2023-09-25" @default.
- W2022989756 title "The syntheses of 2- and 4-trifluoromethylcarbazoles via diphenylamines" @default.
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- W2022989756 doi "https://doi.org/10.1016/s0040-4020(01)93334-4" @default.
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