Matches in SemOpenAlex for { <https://semopenalex.org/work/W2022989846> ?p ?o ?g. }
Showing items 1 to 88 of
88
with 100 items per page.
- W2022989846 endingPage "368" @default.
- W2022989846 startingPage "361" @default.
- W2022989846 abstract "A pair of novel tetrafunctional spiroorthocarbonates (TETRASOC) was prepared in three stages. First, glycerol was reacted with tetraethyl orthocarbonate to form a pair of isomeric hemi spiroorthocarbonates (HEMI SOC-OLs) by monocyclization of glycerol. Formation of these two isomers depends on terminal or adjacent hydroxyl groups of glycerol reacting with the tetraethylorthocarbonate to form five and six-membered ring HEMI SOC-OLs. Second, the HEMI SOC-OLs were made to undergo another cyclization reaction by reacting with 1,3-propanediol, to form a pair of spiroorthocarbonates with one hydroxyl group (SOC-OL). In the third stage, the SOC-OL was used as nucleophylic reactant to displace the bromine atom of pentaerythritol bromide to form the final product TETRASOC. A volume change study was carried out to determine the efficiency of TETRASOC as an anti-shrinking additive finding that even at a low concentration of 7 mol%, it caused a 2.18% expansion of the polymeric volume of a bis epoxycyclohexane monomer (3,4-EP). Dynamic Mechanical Analysis (DMA) determined that the flexibilization induced by the TETRASOC in the polyether derived from 3,4-EP did not adversely impact the mechanical properties of the polymer." @default.
- W2022989846 created "2016-06-24" @default.
- W2022989846 creator A5024708149 @default.
- W2022989846 creator A5025339489 @default.
- W2022989846 creator A5042844143 @default.
- W2022989846 creator A5054805007 @default.
- W2022989846 creator A5061565359 @default.
- W2022989846 creator A5069883592 @default.
- W2022989846 date "2012-03-23" @default.
- W2022989846 modified "2023-10-16" @default.
- W2022989846 title "Novel Tetraspiroorthocarbonates as Successful Anti-shrinking Agents for the Photopolymerization of Epoxy Monomers" @default.
- W2022989846 cites W1972973270 @default.
- W2022989846 cites W1979361074 @default.
- W2022989846 cites W1985431630 @default.
- W2022989846 cites W1987031054 @default.
- W2022989846 cites W1987775988 @default.
- W2022989846 cites W2000319958 @default.
- W2022989846 cites W2009810486 @default.
- W2022989846 cites W2016649941 @default.
- W2022989846 cites W2029916106 @default.
- W2022989846 cites W2035022680 @default.
- W2022989846 cites W2076733668 @default.
- W2022989846 cites W2080042691 @default.
- W2022989846 cites W2086354751 @default.
- W2022989846 cites W2086438849 @default.
- W2022989846 cites W2090026480 @default.
- W2022989846 cites W2163489014 @default.
- W2022989846 cites W2172180765 @default.
- W2022989846 doi "https://doi.org/10.1080/10601325.2012.662082" @default.
- W2022989846 hasPublicationYear "2012" @default.
- W2022989846 type Work @default.
- W2022989846 sameAs 2022989846 @default.
- W2022989846 citedByCount "7" @default.
- W2022989846 countsByYear W20229898462015 @default.
- W2022989846 countsByYear W20229898462017 @default.
- W2022989846 countsByYear W20229898462018 @default.
- W2022989846 countsByYear W20229898462019 @default.
- W2022989846 countsByYear W20229898462021 @default.
- W2022989846 crossrefType "journal-article" @default.
- W2022989846 hasAuthorship W2022989846A5024708149 @default.
- W2022989846 hasAuthorship W2022989846A5025339489 @default.
- W2022989846 hasAuthorship W2022989846A5042844143 @default.
- W2022989846 hasAuthorship W2022989846A5054805007 @default.
- W2022989846 hasAuthorship W2022989846A5061565359 @default.
- W2022989846 hasAuthorship W2022989846A5069883592 @default.
- W2022989846 hasConcept C15487406 @default.
- W2022989846 hasConcept C166595027 @default.
- W2022989846 hasConcept C166940927 @default.
- W2022989846 hasConcept C178790620 @default.
- W2022989846 hasConcept C185592680 @default.
- W2022989846 hasConcept C188027245 @default.
- W2022989846 hasConcept C205474432 @default.
- W2022989846 hasConcept C2776300020 @default.
- W2022989846 hasConcept C2778420591 @default.
- W2022989846 hasConcept C2780881558 @default.
- W2022989846 hasConcept C521977710 @default.
- W2022989846 hasConceptScore W2022989846C15487406 @default.
- W2022989846 hasConceptScore W2022989846C166595027 @default.
- W2022989846 hasConceptScore W2022989846C166940927 @default.
- W2022989846 hasConceptScore W2022989846C178790620 @default.
- W2022989846 hasConceptScore W2022989846C185592680 @default.
- W2022989846 hasConceptScore W2022989846C188027245 @default.
- W2022989846 hasConceptScore W2022989846C205474432 @default.
- W2022989846 hasConceptScore W2022989846C2776300020 @default.
- W2022989846 hasConceptScore W2022989846C2778420591 @default.
- W2022989846 hasConceptScore W2022989846C2780881558 @default.
- W2022989846 hasConceptScore W2022989846C521977710 @default.
- W2022989846 hasIssue "4" @default.
- W2022989846 hasLocation W20229898461 @default.
- W2022989846 hasOpenAccess W2022989846 @default.
- W2022989846 hasPrimaryLocation W20229898461 @default.
- W2022989846 hasRelatedWork W1544605583 @default.
- W2022989846 hasRelatedWork W1986267050 @default.
- W2022989846 hasRelatedWork W1998588133 @default.
- W2022989846 hasRelatedWork W2027959870 @default.
- W2022989846 hasRelatedWork W2047934481 @default.
- W2022989846 hasRelatedWork W2075713167 @default.
- W2022989846 hasRelatedWork W2156735814 @default.
- W2022989846 hasRelatedWork W2388113326 @default.
- W2022989846 hasRelatedWork W2488009843 @default.
- W2022989846 hasRelatedWork W3198618987 @default.
- W2022989846 hasVolume "49" @default.
- W2022989846 isParatext "false" @default.
- W2022989846 isRetracted "false" @default.
- W2022989846 magId "2022989846" @default.
- W2022989846 workType "article" @default.