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- W2022990400 abstract "The title compound [[Cu(shen)]2(tp)], {[Cu(C15H17O4N2)]2}, where tp = dianion of terephthalic acid and shen = (N-salicylidene-N'-(2-hydroxyethyl ethylene-diamine)) has been prepared and its crystal structure determined by single crystal X-ray diffraction at room temperature. The complex crystallizes in the orthorhombic space group Pbca with four formula units in a unit cell of dimensions a = 12.298(2), b = 14.214(2) and c = 16.436(2)Å. The structure consists of binuclear units with Cu(II) ion bridged by the tp ligand in a bis-unidentate fashion. The five coordinate Cu(II) complex adopts a distorted square-based pyramid. A crystallographic inversion center has been located at the center of the benzene ring of the tp bridging ligand. The Cu … Cu distance inside a same binuclear entity is 11.069Å. Intermolecular aromatic ring stacking interactions were observed with the shortest atom to atom contact being 3.423Å." @default.
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- W2022990400 date "2001-11-01" @default.
- W2022990400 modified "2023-09-23" @default.
- W2022990400 title "The Crystal and Molecular Structure of (μ-terephthlato) bis [(N-Salicylidene -N'-(2-hydroxyethyl) ethylenediamine) Copper(II)]" @default.
- W2022990400 doi "https://doi.org/10.1002/1521-4079(200111)36:11<1273::aid-crat1273>3.0.co;2-z" @default.
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