FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W2022994629> ?p ?o ?g. }

• W2022994629 endingPage "9728" @default.
• W2022994629 startingPage "9715" @default.
• W2022994629 abstract "The infrared chemiluminescence in the 1800−3900 cm-1 range was observed from vibrationally excited products generated by the reactions of OH and OD with H2CO in a fast flow reactor with 0.5−1.0 Torr of Ar carrier gas. Computer simulation of the emission spectra from H2O and HOD molecules generated by the primary reaction gave an inverted vibrational distribution in the ν3(O−H) stretching mode of HOD, with a maximum population in v3 = 1; the distribution for the ν1 and ν3 stretch modes of H2O was similar. The vibrational energy disposal to H2O and HOD was 〈fv〉 = 0.54−0.56 with 63% in the newly formed OH bond and 34% in the bending mode. This vibrational distribution is characteristic for a direct abstraction mechanism. The excitation in the bending mode exceeds that from OH reactions with hydrocarbons (<20%), but it is similar to that from the reaction of OH with dimethyl sulfide and HBr. By adjustment of the reaction conditions, infrared emission could be observed from secondary reactions of HCO radical with NO2, NO, OH, and H atoms. The vibrational distributions of H2O and HOD from the primary reaction plus the vibrational distributions of CO2 and CO from the NO2 + HCO reaction, HNO from the NO + HCO reaction, H2O and CO from the OH + HCO reaction, and CO from the H + HCO reaction were analyzed using information theory. The results support an addition mechanism followed by unimolecular decomposition for the HCO radical reactions. The vibrational of H2O distribution from OH + HCO is especially noteworthy, since it can be used to distinguish between direct abstraction vs recombination followed by the decomposition of HCOOH." @default.
• W2022994629 created "2016-06-24" @default.
• W2022994629 creator A5011247910 @default.
• W2022994629 creator A5027618659 @default.
• W2022994629 date "1998-11-01" @default.
• W2022994629 modified "2023-10-14" @default.
• W2022994629 title "Infrared Chemiluminescence Study of the Reactions of Hydroxyl Radicals with Formaldehyde and Formyl Radicals with H, OH, NO, and NO₂" @default.
• W2022994629 cites W1663009739 @default.
• W2022994629 cites W1967023734 @default.
• W2022994629 cites W1968420883 @default.
• W2022994629 cites W1972354450 @default.
• W2022994629 cites W1973950043 @default.
• W2022994629 cites W1973999567 @default.
• W2022994629 cites W1978714173 @default.
• W2022994629 cites W1982690998 @default.
• W2022994629 cites W1985547016 @default.
• W2022994629 cites W1988836671 @default.
• W2022994629 cites W1988988328 @default.
• W2022994629 cites W1991053055 @default.
• W2022994629 cites W1991208986 @default.
• W2022994629 cites W1996032406 @default.
• W2022994629 cites W1996071027 @default.
• W2022994629 cites W1998992616 @default.
• W2022994629 cites W1999029681 @default.
• W2022994629 cites W2002933833 @default.
• W2022994629 cites W2007732857 @default.
• W2022994629 cites W2008176642 @default.
• W2022994629 cites W2008851567 @default.
• W2022994629 cites W2009633753 @default.
• W2022994629 cites W2016786110 @default.
• W2022994629 cites W2018518149 @default.
• W2022994629 cites W2026243009 @default.
• W2022994629 cites W2029023508 @default.
• W2022994629 cites W2029318362 @default.
• W2022994629 cites W2034744277 @default.
• W2022994629 cites W2037128372 @default.
• W2022994629 cites W2038895963 @default.
• W2022994629 cites W2040891652 @default.
• W2022994629 cites W2041538922 @default.
• W2022994629 cites W2041969159 @default.
• W2022994629 cites W2046002177 @default.
• W2022994629 cites W2050486255 @default.
• W2022994629 cites W2053972607 @default.
• W2022994629 cites W2054713188 @default.
• W2022994629 cites W2054914927 @default.
• W2022994629 cites W2055023411 @default.
• W2022994629 cites W2056620994 @default.
• W2022994629 cites W2058051390 @default.
• W2022994629 cites W2058196038 @default.
• W2022994629 cites W2058199827 @default.
• W2022994629 cites W2060924700 @default.
• W2022994629 cites W2065250877 @default.
• W2022994629 cites W2067237929 @default.
• W2022994629 cites W2071597976 @default.
• W2022994629 cites W2073166169 @default.
• W2022994629 cites W2077299935 @default.
• W2022994629 cites W2077325377 @default.
• W2022994629 cites W2077841745 @default.
• W2022994629 cites W2079793505 @default.
• W2022994629 cites W2084707265 @default.
• W2022994629 cites W2090524505 @default.
• W2022994629 cites W2095260255 @default.
• W2022994629 cites W2144079999 @default.
• W2022994629 cites W2297507148 @default.
• W2022994629 cites W3083311034 @default.
• W2022994629 doi "https://doi.org/10.1021/jp982810r" @default.
• W2022994629 hasPublicationYear "1998" @default.
• W2022994629 type Work @default.
• W2022994629 sameAs 2022994629 @default.
• W2022994629 citedByCount "34" @default.
• W2022994629 countsByYear W20229946292013 @default.
• W2022994629 countsByYear W20229946292014 @default.
• W2022994629 countsByYear W20229946292016 @default.
• W2022994629 countsByYear W20229946292017 @default.
• W2022994629 countsByYear W20229946292018 @default.
• W2022994629 countsByYear W20229946292019 @default.
• W2022994629 countsByYear W20229946292020 @default.
• W2022994629 countsByYear W20229946292022 @default.
• W2022994629 crossrefType "journal-article" @default.
• W2022994629 hasAuthorship W2022994629A5011247910 @default.
• W2022994629 hasAuthorship W2022994629A5027618659 @default.
• W2022994629 hasConcept C113196181 @default.
• W2022994629 hasConcept C120665830 @default.
• W2022994629 hasConcept C121332964 @default.
• W2022994629 hasConcept C139066938 @default.
• W2022994629 hasConcept C145802702 @default.
• W2022994629 hasConcept C147789679 @default.
• W2022994629 hasConcept C153642686 @default.
• W2022994629 hasConcept C158355884 @default.
• W2022994629 hasConcept C161790260 @default.
• W2022994629 hasConcept C178790620 @default.
• W2022994629 hasConcept C181500209 @default.
• W2022994629 hasConcept C184779094 @default.
• W2022994629 hasConcept C185592680 @default.
• W2022994629 hasConcept C2775930285 @default.
• W2022994629 hasConcept C32909587 @default.
• W2022994629 hasConcept C65024703 @default.
• W2022994629 hasConcept C75473681 @default.

• next