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- W2022996799 abstract "The rates of pi-electron oxidation and reduction of two homologous series of free base and Zn(II) porphyrins, chlorins, and isobacteriochlorins were studied by chronocoulometry at a platinum disk electrode. The macrocycles were octaethylporphyrin, tetraphenylporphyrin, and the chlorins and isobacteriochlorins derived therefrom. The rates were found to vary to within a factor of 3, and some consistent trends are noted. However, the most important conclusion of this work is that pi-electron redox processes for these macrocycles occur at essentially the same rate, despite the previously noted large differences in pi-electron redox potentials." @default.
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- W2022996799 title "Rates of pi-electron oxidation and reduction of free base and Zn(II) porphyrins, chlorins, and isobacteriochlorins" @default.
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- W2022996799 doi "https://doi.org/10.1016/0162-0134(86)80058-7" @default.
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