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- W2022999946 abstract "Abstract The alkylation of silver(I) trifluoromethanesulfonate by tetraethyllead is studied in a protic (acetic acid) and an aprotic (tetrahydrofuran) medium. Ethane is formed in acetic acid by protonolysis of the ethylsilver intermediate, but the reaction is no truly catalytic [as it is with copper(I)] due to the thermal instability of ethylsilver. The decomposition of ehylsilver in tetrahydrofuran can afford high yields of ethane or butane depending on the concentrations of the reactants. The formations of ethane and butane show different sensitivity toward molecular oxygen. The role of ethyl radicals generated by homolysis of the ethylsilver intermediate is discussed." @default.
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- W2022999946 date "1973-11-01" @default.
- W2022999946 modified "2023-09-26" @default.
- W2022999946 title "Alkylation of silver(I) with tetraethylead" @default.
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- W2022999946 doi "https://doi.org/10.1016/s0022-328x(00)86573-0" @default.
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