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- W2023003649 abstract "Abstract Cyclic voltammetry and spectroelectrochemistry of an electropolymerized film of [Fe 2 (C 10 H 8 )(C 10 H 7 CClCHCHO)] (1) were carried out in acetonitrile with Bu 4 NPF 6 , Bu 4 NBF 4 , Bu 4 NClO 4 or Bu 4 NHSO 4 to determine how the two parameters concerning the stability of the mixed valence state, comproportionation constant, K c , and mixing coefficient, α, depend on the type of counterions. The difference in electrolyte anions causes slight changes in α exhibiting the magnitude of delocalization of charge between two metal centers. However, significant changes in K c , suggest that the ion‐pairing and electrostatic repulsion are main factors that alter the electrochemical stability of the mixed valence state." @default.
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- W2023003649 title "Electrolyte effects on mixed valence state stability of an electropolymerized bis(fulvalene)diiron film" @default.
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- W2023003649 doi "https://doi.org/10.1002/elan.1140080824" @default.
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