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- W2023003837 abstract "Durch Bromierung von γ-Oxosulfonen 1 und anschließende Dehydrohalogenierung werden α,β-ungesättigte γ-Oxosulfone 3 hergestellt. Mit prim, und sek. Aminen reagieren die γ-Oxosulfone 3 zu Enaminoketonen 7; mit Sulfinsäuren 9 tritt Anlagerung zu γ-Oxo-bis-sulfonen 10 ein, und mit Thiolen 11 erhält man γ-Oxo-mercapto-sulfone 12 oder Thioacetale 14. Reactions of α,β-Unsaturated γ-Oxosulfones with Nucleophiles Bromination of the γ-oxosulfones 1 and subsequent dehydrohalogenation leads to the α,β-unsaturated γ-oxosulfones 3. These products react with primary and secondary amines to yield the enaminoketones 7. γ-Oxobissulfones 10 are formed from 3 by addition of the sulfinic acids 9. Thioles 11 react with 3 to give the γ-oxomercaptosulfones 12 or the thioacetals 14." @default.
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- W2023003837 date "1980-01-01" @default.
- W2023003837 modified "2023-09-26" @default.
- W2023003837 title "Reaktionen α,β-ungesättigter γ-Oxosulfone mit Nucleophilen" @default.
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- W2023003837 doi "https://doi.org/10.1002/ardp.19803130807" @default.
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