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- W2023004342 abstract "EPR spectroscopy is applied to Tm impurities in ZnS crystals containing Ag, Li, and La codopants. After optical irradiation, Tm2+ resonances are observed and make it possible to separate different interstitial sites occupied by Tm2+, cubic sites without local charge compensation and axially distorted ones with [111]w and [001] symmetry due to charge compensation by neighboured defects. Additionally a light-insensitive signal could be ascribed to Tm3+ ions, occupying substitutional (Zn)sites, compensated by a negatively charged defect in 〈110〉 directions. From the photoionization spectrum the Tm2+ state is located in the upper half of the band gap. Mit EPR-Spektroskopie werden Tm-Störstellen in ZnS-Kristallen mit Ag, Li und La als Kodotanden untersucht. Nach optischer Einstrahlung werden Tm2+-Resonanzen beobachtet, die es ermöglichen, unterschiedliche Zwischengitterplätze zu separieren, die von Tm2+ besetzt werden: kubische Plätze ohne lokale Ladungskompensation und axial gestörte Plätze mit [111]w- und [001]-Symmetrie, hervorgerufen durch Ladungskompensation benachbarter Defekte. Zusätzlich konnte ein lichtunempfindliches Signal Tm3+ -Ionen zugeordnet werden, die Zn-Substitutionsstörstellen besetzen und durch einen negativ geladenen Defekt in 〈110〉-Richtung kompensiert werden. Aus dem Photoionisationsspektrum wird der Tm2+ -Zustand in der oberen Hälfte der verbotenen Zone angeordnet." @default.
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- W2023004342 date "1994-08-01" @default.
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- W2023004342 title "EPR Spectroscopy of Thulium Impurities in ZnS Crystals" @default.
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- W2023004342 doi "https://doi.org/10.1002/pssb.2221840222" @default.
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