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- W2023004714 abstract "Abstract The thermal decomposition of whole and ground KMnO 4 crystals has been re-examined in an attempt to cause nucleation by pre-irradiation with thermal neutrons, γ-rays, and protons. Decompositions, after irradiations of the solid in the pile, hot-spot, and thermal column, yielded similar p-t plots. The induction period is shortened, and the maximum velocity increased. The acceleration of the decomposition by a reaction proceeding from “irradiation nuclei” appears to be independent of any reaction originating from the nuclei ordinarily operative in unirradiated material. A mechanism involving the annealing of point defects over the induction period is suggested. The activation energy for this process has been determined as 1·31 eV, indicating the migration of vacancies." @default.
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- W2023004714 date "1960-11-01" @default.
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- W2023004714 title "The thermal decomposition of irradiated rubidium permanganate" @default.
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- W2023004714 doi "https://doi.org/10.1016/0022-1902(60)80080-2" @default.
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