FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W2023006569> ?p ?o ?g. }

• W2023006569 endingPage "4034" @default.
• W2023006569 startingPage "4034" @default.
• W2023006569 abstract "Crystals of a cobalt(II) 3-amino-1,2,4-triazolate; Co2Cl(C2N4H3)3, 1 can be formed from a hydrothermal synthesis. X-Ray crystallography shows an extended 3-dimensional network structure within a hexagonal space group with a = 9.9655(7) and c = 7.7523(7) Å. The data reveal an orientational disorder to the ligand. Structural considerations suggest that the ligand orientation is strongly correlated in 1-dimension, but the nature and length scale of the 2-dimensional order is not obvious. The structure is discussed in terms of three key structural models, two of which are crystallographically ordered, while the third is disordered in 2-dimensions. The effect of ligand orientation on the network topology has profound effects on the expected magnetic behaviour, with the two fully ordered models having either antiferromagnetic or ferrimagnetically ordered ground states. The magnetism of 1 is complex. It shows an antiferromagnetically coupled paramagnetic phase above ∼5.3 K. Below ∼4.5 K we see a ferrimagnetically ordered state (Hcoer = 50 Oe, Mrem = 1830 Oe cm3 mol−1, Msat = 3450 Oe cm3 mol−1 at 2 K). In the intermediate temperature range 4.5 to 5.3 K we see unusual behaviour with evidence of rapid, low-energy relaxation of the magnetisation. The unusual relationship between the structure and the magnetism of 1 is discussed in detail." @default.
• W2023006569 created "2016-06-24" @default.
• W2023006569 creator A5026040094 @default.
• W2023006569 creator A5049188079 @default.
• W2023006569 creator A5064625837 @default.
• W2023006569 date "2007-01-01" @default.
• W2023006569 modified "2023-09-26" @default.
• W2023006569 title "Topological ferrimagnetism and superparamagnetic-like behaviour in a disordered homometallic coordination network" @default.
• W2023006569 cites W1539796472 @default.
• W2023006569 cites W1964933396 @default.
• W2023006569 cites W1969521958 @default.
• W2023006569 cites W1975024697 @default.
• W2023006569 cites W1998702263 @default.
• W2023006569 cites W2018230912 @default.
• W2023006569 cites W2019682415 @default.
• W2023006569 cites W2023565621 @default.
• W2023006569 cites W2024716205 @default.
• W2023006569 cites W2026882273 @default.
• W2023006569 cites W2028785018 @default.
• W2023006569 cites W2034689926 @default.
• W2023006569 cites W2037846035 @default.
• W2023006569 cites W2039590858 @default.
• W2023006569 cites W2063334178 @default.
• W2023006569 cites W2071583190 @default.
• W2023006569 cites W2076070702 @default.
• W2023006569 cites W2077422143 @default.
• W2023006569 cites W2078740295 @default.
• W2023006569 cites W2088842078 @default.
• W2023006569 cites W2093470966 @default.
• W2023006569 cites W2097632508 @default.
• W2023006569 cites W2098029361 @default.
• W2023006569 cites W2098726024 @default.
• W2023006569 cites W2102606110 @default.
• W2023006569 cites W2121088430 @default.
• W2023006569 cites W2122820879 @default.
• W2023006569 cites W2126637451 @default.
• W2023006569 cites W2133045527 @default.
• W2023006569 cites W2148066840 @default.
• W2023006569 cites W2164523088 @default.
• W2023006569 cites W2164774489 @default.
• W2023006569 cites W2168442583 @default.
• W2023006569 cites W4210950492 @default.
• W2023006569 doi "https://doi.org/10.1039/b706829h" @default.
• W2023006569 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/17828364" @default.
• W2023006569 hasPublicationYear "2007" @default.
• W2023006569 type Work @default.
• W2023006569 sameAs 2023006569 @default.
• W2023006569 citedByCount "17" @default.
• W2023006569 countsByYear W20230065692013 @default.
• W2023006569 countsByYear W20230065692015 @default.
• W2023006569 countsByYear W20230065692016 @default.
• W2023006569 countsByYear W20230065692020 @default.
• W2023006569 crossrefType "journal-article" @default.
• W2023006569 hasAuthorship W2023006569A5026040094 @default.
• W2023006569 hasAuthorship W2023006569A5049188079 @default.
• W2023006569 hasAuthorship W2023006569A5064625837 @default.
• W2023006569 hasBestOaLocation W20230065692 @default.
• W2023006569 hasConcept C114614502 @default.
• W2023006569 hasConcept C115260700 @default.
• W2023006569 hasConcept C121332964 @default.
• W2023006569 hasConcept C124712363 @default.
• W2023006569 hasConcept C155355069 @default.
• W2023006569 hasConcept C15744967 @default.
• W2023006569 hasConcept C178790620 @default.
• W2023006569 hasConcept C184720557 @default.
• W2023006569 hasConcept C185592680 @default.
• W2023006569 hasConcept C192562407 @default.
• W2023006569 hasConcept C197162081 @default.
• W2023006569 hasConcept C23792430 @default.
• W2023006569 hasConcept C26873012 @default.
• W2023006569 hasConcept C2776029896 @default.
• W2023006569 hasConcept C32546565 @default.
• W2023006569 hasConcept C33923547 @default.
• W2023006569 hasConcept C44280652 @default.
• W2023006569 hasConcept C62520636 @default.
• W2023006569 hasConcept C77805123 @default.
• W2023006569 hasConcept C779372 @default.
• W2023006569 hasConcept C8010536 @default.
• W2023006569 hasConcept C82217956 @default.
• W2023006569 hasConceptScore W2023006569C114614502 @default.
• W2023006569 hasConceptScore W2023006569C115260700 @default.
• W2023006569 hasConceptScore W2023006569C121332964 @default.
• W2023006569 hasConceptScore W2023006569C124712363 @default.
• W2023006569 hasConceptScore W2023006569C155355069 @default.
• W2023006569 hasConceptScore W2023006569C15744967 @default.
• W2023006569 hasConceptScore W2023006569C178790620 @default.
• W2023006569 hasConceptScore W2023006569C184720557 @default.
• W2023006569 hasConceptScore W2023006569C185592680 @default.
• W2023006569 hasConceptScore W2023006569C192562407 @default.
• W2023006569 hasConceptScore W2023006569C197162081 @default.
• W2023006569 hasConceptScore W2023006569C23792430 @default.
• W2023006569 hasConceptScore W2023006569C26873012 @default.
• W2023006569 hasConceptScore W2023006569C2776029896 @default.
• W2023006569 hasConceptScore W2023006569C32546565 @default.
• W2023006569 hasConceptScore W2023006569C33923547 @default.
• W2023006569 hasConceptScore W2023006569C44280652 @default.
• W2023006569 hasConceptScore W2023006569C62520636 @default.
• W2023006569 hasConceptScore W2023006569C77805123 @default.

• next