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• W2023008416 abstract "Binary mixtures of nitrogen with ethane and pentane, respectively, were investigated at pressures up to 200 MPa in an optical high-pressure low-temperature cell according to the synthetic method. The experimental p(T) isopleths show that both systems exhibit upper critical solution temperatures (UCST) at high pressures. The resulting critical curves start at the critical point of the pure alkane, respectively. With decreasing temperatures the critical p(T) curve of the system nitrogen + pentane runs to higher pressures exhibiting a positive curvature whereas the critical curve of the system nitrogen + ethane firstly goes through a slight pressure maximum and minimum successively and then runs steeply to increasing pressures showing a positive curvature, too. The critical curve of the system nitrogen + ethane ends at a critical end point on the three-phase line lls ((176 ± 2) MPa, (105 ± 0.3) K) where two liquid phases become identical in the presence of solid ethane." @default.
• W2023008416 created "2016-06-24" @default.
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• W2023008416 date "1985-01-01" @default.
• W2023008416 modified "2023-09-27" @default.
• W2023008416 title "Fluid Phase Equilibria of the Binary Systems N2 + Ethane and N2 + Pentane Between 88 K and 313 K and at Pressures up to 200 MPa" @default.
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• W2023008416 doi "https://doi.org/10.1002/bbpc.19850890106" @default.
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