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- W2023008552 abstract "Abstract Asymmetric Diels-Alder reaction of the N-dienyl-L-pyroglutamic esters 1a-h with acyl nitroso dienophiles 4a-h gave diastereoisomeric adducts 6a-n, 7a-n with 12–90 % de, depending on solvents and temperature. An interpretation was gived. The “allylic effect” ( π C=C − σ ∗ N-C MO interactions) was found to be effective to account for the conformations of the adducts." @default.
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- W2023008552 date "2010-08-05" @default.
- W2023008552 modified "2023-09-25" @default.
- W2023008552 title "ChemInform Abstract: Chiral N-Dienyl-L-pyroglutamic Esters in Asymmetric Hetero-Diels-Alder Reactions with Acylnitroso Dienophiles." @default.
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- W2023008552 doi "https://doi.org/10.1002/chin.199625200" @default.
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