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- W2023008832 abstract "Pd(II) metallacyclic complexes are key intermediates in sequential reactions in which three new C−C bonds are formed in an aromatic ring. The Pd(II) metallacyclic complex 10 with phenanthroline as ligand undergoes oxidative addition to benzyl bromide or chloride in DMF to generate benzyl-Pd(IV) complexes. The rate constant of the oxidative addition is determined by means of electrochemical techniques, with the expected reactivity order PhCH2Br (k1Br = 3.6 M−1 s−1) > PhCH2Cl (k1Cl = 6 × 10−3 M−1 s−1) at 29 °C. When the benzyl-Pd(IV) complex is generated from PhCH2Br, the oxidative addition is followed by a slow C−C reductive elimination, which gives a Pd(II) complex. The rate constant of the reductive elimination has been determined in DMF (k2Br = 6 × 10−4 s−1) at 29 °C." @default.
- W2023008832 created "2016-06-24" @default.
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- W2023008832 date "2008-08-20" @default.
- W2023008832 modified "2023-10-11" @default.
- W2023008832 title "Rates of the Oxidative Addition of Benzyl Halides to a Metallacyclic Palladium(II) Complex and of the Reductive Elimination from a Benzyl-Palladium(IV) Complex" @default.
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- W2023008832 doi "https://doi.org/10.1021/om800015x" @default.
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