Matches in SemOpenAlex for { <https://semopenalex.org/work/W2023009739> ?p ?o ?g. }
Showing items 1 to 98 of
98
with 100 items per page.
- W2023009739 endingPage "43" @default.
- W2023009739 startingPage "35" @default.
- W2023009739 abstract "The title compounds and their deuterides have been prepared by solid-state and solid–gas reactions from the elements and investigated by X-ray and neutron powder diffraction as a function of temperature. At room temperature they crystallize with an anion-deficient cubic K2PtCl6-type structure (space group Fm3̄m) in which five hydrogen (deuterium) atoms surround iridium randomly on six octahedral sites with average bond distances of Ir–D=169–171 pm. At low temperature they undergo a tetragonal deformation (space group I4/mmm) to the partially ordered Sr2IrD5 (T=4.2K)-type structure in which four hydrogen (deuterium) atoms occupy planar sites with full occupancy (Ir–D=166–170 pm) and two hydrogen (deuterium) atoms axial sites (Ir–D=174–181 pm) with ∼50% occupancy, i.e., the data are consistent with a mixture of square–pyramidal [IrD5]4− complexes pointing in two opposite directions. The transitions occur at ∼240 K (Eu0.5Ca1.5IrD5, Eu0.5Sr1.5IrD5), ∼210 K (EuSrIrD5), ∼200 K (EuCaIrD5, Eu2IrD5), and are presumably of first order." @default.
- W2023009739 created "2016-06-24" @default.
- W2023009739 creator A5016256137 @default.
- W2023009739 creator A5031421025 @default.
- W2023009739 creator A5055853145 @default.
- W2023009739 creator A5058151278 @default.
- W2023009739 date "2003-08-01" @default.
- W2023009739 modified "2023-10-18" @default.
- W2023009739 title "X-ray and neutron powder diffraction study of the order–disorder transition in Eu2IrH5 and the mixed crystal compounds Eu2−xAxIrH5 (A=Ca, Sr; x=1.0, 1.5)" @default.
- W2023009739 cites W1976457756 @default.
- W2023009739 cites W1977166315 @default.
- W2023009739 cites W2003728689 @default.
- W2023009739 cites W2013707685 @default.
- W2023009739 cites W2045466546 @default.
- W2023009739 cites W2074453358 @default.
- W2023009739 cites W2078523742 @default.
- W2023009739 cites W2088301459 @default.
- W2023009739 cites W2137061288 @default.
- W2023009739 cites W2161584145 @default.
- W2023009739 cites W2167590372 @default.
- W2023009739 cites W2322094164 @default.
- W2023009739 cites W2950713965 @default.
- W2023009739 cites W2950899239 @default.
- W2023009739 cites W2953007745 @default.
- W2023009739 cites W4295093928 @default.
- W2023009739 cites W2147177564 @default.
- W2023009739 doi "https://doi.org/10.1016/s0022-4596(03)00171-3" @default.
- W2023009739 hasPublicationYear "2003" @default.
- W2023009739 type Work @default.
- W2023009739 sameAs 2023009739 @default.
- W2023009739 citedByCount "26" @default.
- W2023009739 countsByYear W20230097392012 @default.
- W2023009739 countsByYear W20230097392013 @default.
- W2023009739 countsByYear W20230097392014 @default.
- W2023009739 countsByYear W20230097392017 @default.
- W2023009739 countsByYear W20230097392018 @default.
- W2023009739 countsByYear W20230097392020 @default.
- W2023009739 countsByYear W20230097392022 @default.
- W2023009739 crossrefType "journal-article" @default.
- W2023009739 hasAuthorship W2023009739A5016256137 @default.
- W2023009739 hasAuthorship W2023009739A5031421025 @default.
- W2023009739 hasAuthorship W2023009739A5055853145 @default.
- W2023009739 hasAuthorship W2023009739A5058151278 @default.
- W2023009739 hasConcept C112887158 @default.
- W2023009739 hasConcept C115624301 @default.
- W2023009739 hasConcept C120665830 @default.
- W2023009739 hasConcept C121332964 @default.
- W2023009739 hasConcept C170751736 @default.
- W2023009739 hasConcept C178790620 @default.
- W2023009739 hasConcept C184779094 @default.
- W2023009739 hasConcept C185039092 @default.
- W2023009739 hasConcept C185592680 @default.
- W2023009739 hasConcept C198819137 @default.
- W2023009739 hasConcept C207114421 @default.
- W2023009739 hasConcept C32909587 @default.
- W2023009739 hasConcept C50515024 @default.
- W2023009739 hasConcept C512968161 @default.
- W2023009739 hasConcept C58364064 @default.
- W2023009739 hasConcept C73585123 @default.
- W2023009739 hasConcept C8010536 @default.
- W2023009739 hasConceptScore W2023009739C112887158 @default.
- W2023009739 hasConceptScore W2023009739C115624301 @default.
- W2023009739 hasConceptScore W2023009739C120665830 @default.
- W2023009739 hasConceptScore W2023009739C121332964 @default.
- W2023009739 hasConceptScore W2023009739C170751736 @default.
- W2023009739 hasConceptScore W2023009739C178790620 @default.
- W2023009739 hasConceptScore W2023009739C184779094 @default.
- W2023009739 hasConceptScore W2023009739C185039092 @default.
- W2023009739 hasConceptScore W2023009739C185592680 @default.
- W2023009739 hasConceptScore W2023009739C198819137 @default.
- W2023009739 hasConceptScore W2023009739C207114421 @default.
- W2023009739 hasConceptScore W2023009739C32909587 @default.
- W2023009739 hasConceptScore W2023009739C50515024 @default.
- W2023009739 hasConceptScore W2023009739C512968161 @default.
- W2023009739 hasConceptScore W2023009739C58364064 @default.
- W2023009739 hasConceptScore W2023009739C73585123 @default.
- W2023009739 hasConceptScore W2023009739C8010536 @default.
- W2023009739 hasIssue "1" @default.
- W2023009739 hasLocation W20230097391 @default.
- W2023009739 hasOpenAccess W2023009739 @default.
- W2023009739 hasPrimaryLocation W20230097391 @default.
- W2023009739 hasRelatedWork W1956143343 @default.
- W2023009739 hasRelatedWork W1977790219 @default.
- W2023009739 hasRelatedWork W1984854152 @default.
- W2023009739 hasRelatedWork W2066483243 @default.
- W2023009739 hasRelatedWork W2069218452 @default.
- W2023009739 hasRelatedWork W2089940889 @default.
- W2023009739 hasRelatedWork W2136694185 @default.
- W2023009739 hasRelatedWork W2505301980 @default.
- W2023009739 hasRelatedWork W2585356355 @default.
- W2023009739 hasRelatedWork W4211231660 @default.
- W2023009739 hasVolume "174" @default.
- W2023009739 isParatext "false" @default.
- W2023009739 isRetracted "false" @default.
- W2023009739 magId "2023009739" @default.
- W2023009739 workType "article" @default.