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• W2023010107 startingPage "4556" @default.
• W2023010107 abstract "The new molecular dihydrogen complex [TpOs(H2)(PPh3)2]BF4 was prepared by protonation of TpOsH(PPh3)2 with HBF4. The pseudo-aqueous pKa values of [CpOsH2(PR3)2)]BF4 ((PR3)2 = (PPh3)2, dppm, dppe, dppp) and [TpOs(H2)(PPh3)2]BF4 have been determined in dichloromethane. [TpOs(H2)(PPh3)2]BF4 was found to be more acidic than trans-[CpOsH2(PPh3)2]BF4. While [TpOs(H2)(PPh3)2]BF4 is less acidic than [TpRu(H2)(PPh3)2]BF4 by 1.3 pKa units, trans-[CpOsH2(PPh3)2]BF4 is less acidic than trans-[CpRuH2(PPh3)2]BF4 by 5.1 pKa units." @default.
• W2023010107 created "2016-06-24" @default.
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• W2023010107 date "1998-09-17" @default.
• W2023010107 modified "2023-10-17" @default.
• W2023010107 title "Ligand Effect on the Structures and Acidities of [TpOs(H₂)(PPh₃)₂]BF₄ and [CpOsH₂(PR₃)₂]BF₄" @default.
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• W2023010107 doi "https://doi.org/10.1021/om9804071" @default.
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