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- W2023010348 abstract "We appreciably broaden the scope of existing thermodynamic perturbation theory for pure fluids in several ways. Analytical approximation strategies are combined to express the thermodynamic properties of fluids in analytical and/or algebraic form and applied to a generalized class of pair potentials. The results are illustrated by comparing previously reported simulation measurements with our predictions obtained using a new class of generalized Lennard-Jones potential functions with independently adjustable repulsive and attractive length scales. Results are also obtained for various purely repulsive fluids, including inverse-power potentials with exponents ranging from 12 to 72 and a Lennard-Jones repulsive reference fluid. Applications to argon (Lennard-Jones) and C60 (Girifalco potential) are used to probe the limits of applicability of first-order perturbation theory to systems with very short range attractive potentials. Furthermore, we discuss the role of these new results in a number of additional applications." @default.
- W2023010348 created "2016-06-24" @default.
- W2023010348 creator A5023716556 @default.
- W2023010348 creator A5057965332 @default.
- W2023010348 date "2003-11-07" @default.
- W2023010348 modified "2023-10-17" @default.
- W2023010348 title "Analytical implementation and critical tests of fluid thermodynamic perturbation theory" @default.
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- W2023010348 doi "https://doi.org/10.1063/1.1620995" @default.
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