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- W2023012314 abstract "Abstract The effect of the vanadium content on the cyclic stability of V–Ti binary alloys was investigated. V 1− x Ti x , x = 0.2 and 0.5 samples were hydrogenated and dehydrogenated at 410 K and 553 K respectively, for more than 100 times. During hydrogen cycling, reduction in the reversible hydrogen storage capacity was clearly observed from both samples. No prominent V-effect was found. In fact, the reduction rates of two samples were similar; both samples showed a ∼25% reduction in the reversible hydrogen storage capacity after 100 cycles. In addition, the shape of the pressure–composition-isotherm (PCT) curves was significantly altered over the testing cycle period; the absorption and desorption plateaus got markedly inclined and the hysteresis became evidently smaller. We found that even after the hydrogen storage capacity of V 1− x Ti x was significantly reduced, at low enough temperature V 1− x Ti x was able to absorb hydrogen as much as it did at the first cycle. Furthermore, the reversible hydrogen storage capacity of V 0.8 Ti 0.2 at 410 K was recovered to a certain degree after hydrogenating the sample at low temperatures." @default.
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- W2023012314 date "2014-07-01" @default.
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- W2023012314 title "Reduction and unusual recovery in the reversible hydrogen storage capacity of V1−Ti during hydrogen cycling" @default.
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- W2023012314 doi "https://doi.org/10.1016/j.ijhydene.2014.04.128" @default.
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