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- W2023013507 abstract "Abstract The stereoselective synthesis of (−)-protoemetinol has been accomplished through nine steps from a known homoallylic amine. The key steps of the synthesis involve the efficient preparation of an aza-Claisen rearrangement (ACR) precursor using cross metathesis and amide enolate-induced ACR followed by acid-catalyzed transannulation for the elaboration of the benzo[α]quinolizine skeleton and three stereogenic centers. This unique synthetic route envisages a unified and versatile strategy for the synthesis of 2,3-disubstituted benzo[α]quinolizidine." @default.
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- W2023013507 date "2015-01-01" @default.
- W2023013507 modified "2023-10-16" @default.
- W2023013507 title "Efficient strategy for the stereoselective synthesis of 2,3-disubstituted benzo[α]quinolizidine alkaloids: concise synthesis of (−)-protoemetinol" @default.
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- W2023013507 doi "https://doi.org/10.1016/j.tetlet.2014.12.030" @default.
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