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- W2023015665 abstract "The newly prepared water-soluble naphthalene tweezer 2a and anthracene clip 4a (substituted both with lithium methanephosphonate groups in the central spacer unit) undergo an unexpected self-assembly in aqueous solution. The highly ordered intertwined structures of the self-assembled dimers [2a]2 and [4a]2 were elucidated by quantum chemical 1H NMR shift calculations. 2a and 4a form extremely stable host−guest complexes with N-methylnicotinamide 8 in methanol and water as well. According to the thermodynamic parameters determined by 1H NMR titration experiments at various temperatures the self-assembly of 2a and 4a and their strong binding to NMNA 8 observed in aqueous solution are enthalpy driven (ΔH ≪ 0); the enthalpic driving force is partially compensated by an unfavorable entropy (TΔS < 0). Self-assembly and the host−guest binding are therefore beautiful examples of the nonclassical hydrophobic effect." @default.
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- W2023015665 date "2006-03-16" @default.
- W2023015665 modified "2023-10-18" @default.
- W2023015665 title "Molecular Tweezer and Clip in Aqueous Solution: Unexpected Self-Assembly, Powerful Host−Guest Complex Formation, Quantum Chemical <sup>1</sup>H NMR Shift Calculation" @default.
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- W2023015665 doi "https://doi.org/10.1021/ja058410g" @default.
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