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- W2023018044 abstract "CuCl and bis(diphenylphosphanyl)methane (dppm) react in the presence of small amounts of FeCl3 with PhSeSiMe3 and Se(SiMe3)2 to yield [Cu30Fe2Se6(SePh)24(dppm)4]. The crystal structure of the compound was determined by single-crystal X-ray analysis to give a mixed copper selenide/selenolate cluster molecule of a new structural type incorporating two central iron atoms. The formal oxidation state of the iron atoms was determined by Mössbauer spectroscopy to be +3, in agreement with quantum chemical calculations and modeling of the magnetic data. In addition, Mössbauer studies show no magnetic hyperfine structure in zero field, and the magnetically perturbed spectrum displays a pattern typical for a diamagnetic species in a transverse field, suggesting a singlet ground state. However, the inclusion of the iron atoms has a distinct influence on the optical properties of the compound compared to similar clusters containing only copper and selenium atoms." @default.
- W2023018044 created "2016-06-24" @default.
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- W2023018044 date "2009-08-19" @default.
- W2023018044 modified "2023-09-25" @default.
- W2023018044 title "Synthesis and Structure of an “Iron-Doped” Copper Selenide Cluster Molecule: [Cu<sub>30</sub>Fe<sub>2</sub>Se<sub>6</sub>(SePh)<sub>24</sub>(dppm)<sub>4</sub>]" @default.
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- W2023018044 doi "https://doi.org/10.1021/ic900890n" @default.
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