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- W2023018217 abstract "Time‐resolved nsec kinetic methods are used to measure state specific electronic excitation transfer for the near‐resonant process: Ca(4s5p 1P1) +Ar ⇄k-1k1 Ca(4s5p 3P2,1,0)+Ar. In stimulated emission experiments it is found that the Ca(4s5p 3P2) level is preferentially populated. The rate constant k1 for the specific 3P2 channel is 5.2±0.5×10−11 cm3 molecule−1 sec−1. These results are discussed in terms of near‐resonant spin changing collision mechanisms. Radiative lifetimes for Ca(4s5p 1P1) and Ca(4s5p 3P1) are also determined to be 77±2 nsec and 67±2 nsec, respectively." @default.
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- W2023018217 date "1981-05-15" @default.
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- W2023018217 title "Laser studies of electronic excitation transfer in atomic calcium: Ca(4s5p 1P1)+Ar⇄Ca(4s5p 3P2, 1, 0)+Ar" @default.
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- W2023018217 doi "https://doi.org/10.1063/1.440935" @default.
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