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- W2023049258 abstract "A theory based on Kirkwood's mean-field approximation is presented in order to elucidate the nature of a solid-state phase transition associated with rotational fluctuations about chain axes. Simultaneous equations describing states of the system are obtained and are solved for several restricted cases. A first-order phase transition with the latent heat of 19 cal/CH 2 mol is predicted at 339 K for C 22 n -paraffine; it well explains the empirical rotational phase transition, but the latent heat is far less than experimental values." @default.
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- W2023049258 title "Phase Transition in Crystals of Semiflexible Long-Chain Molecules. I" @default.
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- W2023049258 doi "https://doi.org/10.1143/jpsj.43.627" @default.
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