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- W2023073412 abstract "3-methyl-2'-deoxyguanosine (1a) is obtained from 2'-deoxyguanosine by a reaction sequence involving conversion into tricyclic 1,N-2-isopropeno derivative (4-desmethyl-2'-deoxywyosine, 3a) followed by methylation which results in 2'-deoxywyosine (2a) and final removal of the 1,N-2 blocking system. Compounds 1a and 2a undergo spontaneous hydrolytic cleavage of their glycosidic bonds at pH 7, 37 degrees C, which makes them the most labile of all known nucleosides composed of structural units occurring in nature." @default.
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- W2023073412 date "1990-01-01" @default.
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- W2023073412 title "Chemical synthesis and spontaneous glycosidic hydrolysis of 3-methyl-2′-deoxyguanosine and 2′-deoxywyosine [1]" @default.
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- W2023073412 doi "https://doi.org/10.1093/nar/18.16.4779" @default.
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