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- W2023083970 abstract "2H NMR reveals two dynamic crossovers of supercooled water in nanoscopic (∼2 nm) confinement. At ∼225 K, a dynamic crossover of liquid water is accompanied by formation of a fraction of solid water. Therefore, we do not attribute the effect to a liquid–liquid phase transition but rather to a change from bulk-like to interface-dominated dynamics. Moreover, we argue that the α process and β process are observed in experiments above and below this temperature, respectively. Upon cooling through a dynamic crossover at ∼175 K, the dynamics of the liquid fraction becomes anisotropic and localized, implying solidification of the corresponding water network, most probably, during a confinement-affected glass transition." @default.
- W2023083970 created "2016-06-24" @default.
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- W2023083970 creator A5060785129 @default.
- W2023083970 date "2013-12-17" @default.
- W2023083970 modified "2023-10-18" @default.
- W2023083970 title "Dynamic Crossovers and Stepwise Solidification of Confined Water: A <sup>2</sup>H NMR Study" @default.
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- W2023083970 doi "https://doi.org/10.1021/jz402539r" @default.
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