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- W2023085082 endingPage "320" @default.
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- W2023085082 abstract "Herein we describe the recent mechanistic understandings of the singlet oxygen ene reaction to give hydroperoxides and the [4+2] cycloaddition affording endoperoxides. Both experimental findings and theoretical work conclude in the formation of intermediates structurally similar to perepoxides during the ene reaction. Such intermediates mainly control the regio- and stereoselectivities of this reaction class. For the [4+2] cycloaddition, both a synchronous concerted reaction (benzene, naphthalenes) and a stepwise reaction with a non-symmetric zwitterionic intermediate (larger acenes) have been found. The thermolysis of endoperoxides derived from acenes proceeds stepwise for anthracenes, but in a concerted manner for less stable adducts such as naphthalene." @default.
- W2023085082 created "2016-06-24" @default.
- W2023085082 creator A5010410372 @default.
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- W2023085082 date "2014-01-01" @default.
- W2023085082 modified "2023-09-30" @default.
- W2023085082 title "Intermediates in the Formation and Thermolysis of Peroxides from Oxidations with Singlet Oxygen" @default.
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- W2023085082 doi "https://doi.org/10.1071/ch13423" @default.
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