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- W2023087680 abstract "Der Arsinidenkomplex [Cp′(CO)2Mn]2AsCl, 1, (Cp′ C5H4CH3) reagiert mit TIPF6 zunächst unter Bildung eines Salzes von [Cp′(CO)2MnAsMn(CO)2Cp′]+, das bei längerer Reaktionszeit in den Fluorarsinidenkomplex [Cp′(CO)2Mn]2AsF, 3, übergeht. Einfacher wird 3 aus 1 und TIF erhalten. Die Struktur des Salzes [Cp′(CO)2MnAsMn(CO)2Cp]+CF3SO3−, 2, das aus Chloridabstraktion aus 1 erhalten worden war, wird diskutiert. Einen Zugang zu Komplexen 5 mit dem [CP*(CO)2MnAsMn(CO)2Cp*]+-Kation (Cp* C5(CH3)5) bietet die Hydridabstraktion aus [Cp*(CO)2Mn]2AsH, 4, mit den Carbenium-Ion-Äquivalenten Et3OBF4, Ph3CPF6 und CF3SO3CH3 sowie mit den Säuren CF3SO3H und H2SO4. Dimetalla-Arsa-Cumulenium Ions The arsinidene compound [Cp′(CO)2Mn]2AsCl, 1, (Cp′ C5H4CH3) reacts with TIPF6 under initial formation of a salt of [Cp′(CO)2MnAsMn(CO)2Cp′]+, which upon prolonged reaction time transforms into the fiuoroarsinidene compound [Cp′(CO)2Mn]2AsF, 3. 3 is more easily accessible from 1 and TIF. The structure of [Cp′(CO)2MnAsMn(CO)2Cp]+CF3SO3−, 2, which had been synthesized by chloride abstraction from 1, will be discussed. A synthetic route to compounds 5 containing the [Cp*(CO)2MnAsMn(CO)2Cp*]+-cation (Cp* C5(CH3)5) consists in hydride abstraction from [Cp*(CO)2Mn]2AsH, 4, by the carbenium ion equivalents Et3OBF4, PhCPF6 and CF3SO3SH3 or by the acids CF3SO3H and H2SO4." @default.
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- W2023087680 date "1989-10-01" @default.
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- W2023087680 title "Dimetalla-Arsa-Cumulenium-Ionen" @default.
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- W2023087680 doi "https://doi.org/10.1002/zaac.19895770130" @default.
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