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- W2023103067 abstract "Anion–π interactions have been receiving a great deal of attention from the scientific community for the past five years. This type of non-covalent bond is being recognized as a supramolecular interaction by chemists. Remarkably, the status for the lone pair(lp)-π interaction, namely the bonding association between a neutral electron-rich molecule and an electron-poor π ring, is hardly studied. The importance of lp–π interactions was clearly evidenced in a number of biological systems more than ten years ago; amazingly, only a few examples of lp–π interactions involving small synthetic molecules have been reported so far in the literature. Are these examples unique? Actually, a detailed analysis of the Cambridge Structure Database shows that such interactions are not unusual in organic compounds, but apparently have been overlooked in the past." @default.
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- W2023103067 date "2008-01-01" @default.
- W2023103067 modified "2023-10-16" @default.
- W2023103067 title "Lone pair–π interactions: a new supramolecular bond?" @default.
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- W2023103067 doi "https://doi.org/10.1039/b812026a" @default.
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