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- W2023105481 abstract "The kinetic behaviour is predicted for a hypothetical polymer reaction in which the reactivity of a substituent (or other reacting entity) depends on whether zero, one or two of its neighbours have already reacted. The problem is not new, but the method of analysis used here gives solutions applicable to reactions of polymer molecules containing a finite number m, as well as an infinite number (m→∞), of substituents. Results are given showing the variety of plots that can be expected for the extent ξ and the rate [graphic omitted] of reaction, and for the number Nx of sequences of x unreacted substituents. Depending on the relative probabilities of reaction, the overall reaction kinetics can show co-operative (autocatalytic), autoretarding (antico-operative) or random behaviour. Random reaction involving single substituents gives overall first-order kinetics. The mathematical treatment belongs to a class of kinetics and statistics of occupation of a one-dimensional array: the terminology is easily changed from reaction to occupation kinetics." @default.
- W2023105481 created "2016-06-24" @default.
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- W2023105481 date "1972-01-01" @default.
- W2023105481 modified "2023-10-17" @default.
- W2023105481 title "Reaction kinetics of polymer substituents. Neighbouring-substituent effects in single-substituent reactions" @default.
- W2023105481 doi "https://doi.org/10.1039/f19726802295" @default.
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