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- W2023109137 abstract "Photoinduced electron transfer between transition metal ions and polycyclic aromatic hydrocarbons (PAHs) was utilized to induce the photodegradation of phenanthrene (PHE), a tricyclic aromatic hydrocarbon, under visible light irradiation (λ > 420 nm). Experimental results indicate that Fe3+ ions possess excellent ability of sensitization in the photodegradation of PHE. In solution, PHE could be oxidated completely by oxygen after 3 h irradiation. The intermediates of PHE photodegradation were detected by gas chromatography−mass spectrometer. Eleven kinds of intermediates were determined, including one decomposition product, five ring-opening products, and other oxidation derivatives. Phenanthrenequinone and (1,1‘-biphenyl)-2,2‘-dicarboxaldehyde were the two main products. Based on the experiment results, a possible mechanism was proposed. In alcohols and acetic acid, the photodegradation efficiency of PHE was low, probably because that active PHE•+ was quenched in these solvents. The impacts of variable f..." @default.
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- W2023109137 date "2008-02-22" @default.
- W2023109137 modified "2023-10-16" @default.
- W2023109137 title "Efficient Photodegradation of Phenanthrene under Visible Light Irradiation via Photosensitized Electron Transfer" @default.
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- W2023109137 doi "https://doi.org/10.1021/jp7111022" @default.
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