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- W2023112222 abstract "The phase reactions, crystallization behaviour and thermal degradation of two Si–C–N ceramics derived from precursors VT50 and NCP200, respectively, were studied by means of CALPHAD type thermodynamic calculations and experimental investigations by DTA/TG, XRD and SEM/EDX. The phase reaction Si3N4+3C=3SiC+2N2 proceeds during the thermal degradation of both ceramics. Additionally, the phase reaction Si3N4=3Si+2N2 occurs during the thermal degradation of the NCP200 ceramic. To explain quantitatively the high temperature behaviour of Si–C–N ceramics, thermodynamic functions, the reaction scheme, isothermal sections, isopleths, phase fraction diagrams and phase composition diagrams (for gas partial pressures) were calculated. The computer simulations were confirmed by the experiments for both ceramics." @default.
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- W2023112222 date "2001-05-01" @default.
- W2023112222 modified "2023-10-01" @default.
- W2023112222 title "Phase equilibria and thermal analysis of Si–C–N ceramics" @default.
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- W2023112222 doi "https://doi.org/10.1016/s0925-8388(00)01478-x" @default.
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