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- W2023112228 abstract "The stereoselective syntheses of four unusual amino acids, constituents of cyclomarin A, are described. The protected N-methylhydroxyleucine 2 was synthesized using Evans’ asymmetric azide-transfer reaction. The unusual amino acid 3 was prepared via diastereoselective methylation of the l-aspartic acid derived lactone 13. The stereoselective formation of threo-β-methoxyphenylalanine 4 was performed via aldol reaction using Schöllkopf's chiral glycine enolate. The synthesis of N-reverse prenylated tryptophane 5 was achieved by the AQN ligand-promoted Sharpless regioreversed asymmetric aminohydroxylation protocol." @default.
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- W2023112228 date "2002-05-01" @default.
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- W2023112228 title "Syntheses of four unusual amino acids, constituents of cyclomarin A" @default.
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- W2023112228 doi "https://doi.org/10.1016/s0040-4039(02)00607-x" @default.
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