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- W2023121538 abstract "Facilitated or complexation-mediated transport of oxygen in the solid membrane containing a fixed carrier was described, by using the polymer-bound cobalt Schiff's base chelate (CoS) and cobaltporphyrin (CoP). α3 β-Substituted cobaltporphyrin derivatives were synthesized: The oxygen-binding reaction to cobalt was affected by the cavity structure on porphyrin, i.e., unbulky amido-substituted groups such as acetylamido- and acrylamido-substituents enhanced oxygen-binding and -dissociation rate constant or provided an oxygen-binding pathway. Oxygen transport through the membranes of these polymer-bound CoP derivatives was selectively augmented due to the rapid and reversible oxygen-binding. Diffusion constants via the fixed CoPs correlated to the characteristics of oxygen-binding reaction." @default.
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- W2023121538 date "1994-03-01" @default.
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- W2023121538 title "O2 /n2 -separation by polymer-bound cobalt complexes" @default.
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- W2023121538 doi "https://doi.org/10.1002/masy.19940800111" @default.
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